property Columns.Item (Index as Variant) as Column
Returns a specific Column of the Columns collection.

TypeDescription
Index as Variant A long expression that indicates the column's index or a string expression that indicates the column's key or the column's caption.
Column A column object being returned.
Use the Item property to access to a specific column.  The Count property counts the columns in the control. Use the Columns property to access the control's Columns collection.

The Item property is the default property of the Columns object so the following statements are equivalents:

.Columns.Item ("Freight")
.Columns ("Freight")