property CalcCombo.Buttons as String
Specifies the list of buttons in the control.

TypeDescription
String A string expression that indicates the list of buttons being displayed. The rows are separated by chr(13)+chr(10) ( vbCrLf ) sequence, and the buttons inside the row are separated by ';' character.
The Buttons property specifies the buttons and the layout of the buttons in the control. Use the PictureDown and PictureUp properties to specify the picture for the buttons. Use the ButtonHeight and ButtonWidth property to specify the height and the width of the buttons in the control. The ClickButton event occurs when the user clicks a button in the calculator.

Each button supports built-in HTML format like follows:

By default, the Buttons property is "<fgcolor=0000FF><b>7</b></fgcolor>;<fgcolor=0000FF><b>8</b></fgcolor>;<fgcolor=0000FF><b>9</b></fgcolor>;<fgcolor=FF0000>/</fgcolor>;C\r\n<fgcolor=0000FF><b>4</b></fgcolor>;<fgcolor=0000FF><b>5</b></fgcolor>;<fgcolor=0000FF><b>6</b></fgcolor>;<fgcolor=FF0000>*</fgcolor>;1/x\r\n<fgcolor=0000FF><b>1</b></fgcolor>;<fgcolor=0000FF><b>2</b></fgcolor>;<fgcolor=0000FF><b>3</b></fgcolor>;<fgcolor=FF0000>-</fgcolor>;sqrt\r\n<fgcolor=0000FF><b>0</b></fgcolor>;<fgcolor=0000FF><b>+/-</b></fgcolor>;<fgcolor=0000FF><b>.</b></fgcolor>;<fgcolor=FF0000>+</fgcolor>;<fgcolor=000080><b>=</b></fgcolor>"

Use the Caption property to access the control's caption. Use the Execute method to execute operations inside the control. 

The following sample adds a new button 'sin' and execute the trigonometric sin function when 'sin' button is clicked:

Private Sub Form_Load()
    With CalcCombo1
        .Buttons = .Buttons + vbCrLf + "<b>sin<b>"
    End With
End Sub

Private Sub CalcCombo1_ClickButton(ByVal Button As String, Cancel As Variant)
    If (Button = "sin") Then
        With CalcCombo1
            .Execute Sin(.Caption)
        End With
    End If
End Sub